I don't have any experience with poured liners, but, I have removed and replaced several flexible chimney liners that were only a few years old. After what I have seen with the flexible liners, I would never put one in for myself unless there was no other choice. Like many things in construction, you get what you pay for.
Only further advice I have is that if you have to hire someone to do the job, ask them about their experience - ask them to see pictures of their work on previous jobs, choose a contractor that has been doing this kind of work for several years, choose a contractor that is licensed, bonded, and insured, and shop local whenever possible (traveling for work cost money that gets charged to the homeowner one way or another). Some things you can get by with going cheap, or inexperienced to save some money. When it comes to burning down your home if things are not done right - not worth the savings. You could ask your local fireplace dealer or HVAC contractor for references and recommendations to help you find the right guy to do the job at a fair price and avoid the hacks.